Ion Implantation

PVD CVD Etch Ion Implantation Electrostatic Chuck


Ion Implantation

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The following is an excerpt from a paper I wrote on damage induced ion implantation in silicon.

Background:

- The ion-implantation process is concerned with introducing predetermined concentrations of a dopant with the desired profile at a specified distance from the silicon surface.

- The implantation process requires high energy ions to be imbedded in the Si lattice.

- By reason of the high impact (momentum transfer) between the Si lattice atoms and implanted ions, damage to the crystalline lattice ensue.

- Theoretical modeling allows calculation of the concentration distribution along the path of the ions in the Si lattice (the theoretical model is called the range theory, or the LSS theory after its founders). The model is built on the assumption that the lattice is amorphous. Also, models exist to explain the accompanying spatial distribution of damage to the lattice.

- The spatial distribution of the implant and the damage distribution in the lattice do not necessarily overlap.


Parameters for the Estimation of Ion and Deposited Energy Distributions

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Penetration Range (or Range), R:  The Range is defined as the total distance traveled by the charged ion of the dopant before it comes to rest in an amorphous target. Factors affecting R include: (a) Nuclear stopping power results from the collisions with the target atoms, and  (b) Electronic stopping power results from the interaction of the ion with the bound and free electrons of the target atoms. Each of the stopping powers is defined as the energy of the ion at any point along its path until it comes to rest.

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Projected range, Rp, and Straggle:  Rp is the projection of R along the direction of the incident ion. Since the nature of implantation is statistical, the projected range, Rp, is characterized by its mean value, i.e. the location of the maximum concentration, and its standard deviation called the straggle, Rp. Moreover, there is a lateral spread termed Rt related to the doping distribution near the edge of the mask.

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Channeling: Is the situation when the direction of implanted ions coincides with a direction in the crystalline lattice allowing the ions to pass through the lattice unimpeded. To avoid channeling, the Si wafer (of the 100-cut) is tilted by 7 to 10 degrees from the incoming beam of ions.

A Description of the Nuclear and Electronic Stopping Powers of the Crystal Lattice Target

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As the energetic ion enters the Si, it first transfers energy to the lattice relatively slowly. As the ion slows down, the rate of energy transfer increases until the ion comes to rest.

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The electron clouds of the Si-atoms also contribute to the slowing down of the implanted ion. The electron clouds of the Si atoms screen the repulsive forces between the nuclei of the implanted atoms and the Si-atoms resulting in a constant rate of energy loss. This retardation process is called the approximate nuclear stopping power. The energy loss rate of this process is about 10-100 eV per Å, and the value depends on the ion-target combination.

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The implanted ions with energies between 50 and 500 keV have suficient energy to excite and ionize the Si-atoms.

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The projected range, Rp, is calculated from both the nuclear and electronic stopping powers. Ions with high energy are retarded by the electronic stopping power, while ions with low energies are retarded by the nuclear collisions, or the nuclear stopping power.

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The range, R, is proportional to the square root of the energy of the implanted ion, while at lower energies the range is linearly proportional to the energy.

Lattice Damage due to Implantation

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Damage is directly proportional to the amount of kinetic energy transferred to the lattice at a given depth.

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The implantation energies are sufficient to create an amorphous layer; this layer is restored to a (sufficiently) crystalline state by annealing at a high temperature. The annealing process also activates the dopant, that is, restores electrons and holes (carriers) mobilities and lifetimes. (Recall that the energy band model for semiconducting materials is built on a perfect crysalline state, and dopants occupy the substitutional sites.) These two responses to thermal activation occur in parallel.

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A threshold fluence is defined as that dose (units are in cm-1)at which a wholly first amorphous layer first appears. That fluence depends on the nature of the ion (the lighter the ion the higher the required fluence), and the temperature of the target during implantation (the higher the temperature the higher the threshold fluence). The product of the threshold fluence by the nuclear stopping power gives the critical energy density. The threshold damage density (TDD) indicates the existence of a crystalline-amorphous interface; the TDD is an energy density term, and is reported with the ion-energy, dose, and substrate temperature during implantation.

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Annealing implanted Si is extensively researched.

 

References

  1. J. Linhard, M. Scharff, and H.E. Schiott, Medd. Dan. Vidensk. Selsk., 33:1 (1963). (The original paper for the LSS model.)
  2. S.K. Ghandi, VLSI Fabrication Principles, Si and Ga As, John Wiley and Sons, N.Y. (1983).
  3. G.E. McGuire (ed.), Semiconductor Materials and Process Technology Handbook for VLSI and ULSI, Noyse Publications, N.J. (1988).
  4. F.H. Eisen and L.T. Chaderton (eds.), Ion Implantation, Gordon and Breach, London (1971)
  5. D.K. Brice, Ion Implanation Range and Energy Deposition, Vol. I, Plenum Press, N.Y. (1975)
  6. J.F. Ziegler et al., The Stopping and Range of Ions in Solids, Pergamon Press, N.Y. (1984)
  7. S. Prussin et al., J. Appl. Phys., 57:180 (1985) (Reviews of damage in silicon and its classification)

 

 

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